Reaction
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RuPhos Pd G3

Reaction
Product Name
RuPhos Pd G3
CAS No.
1445085-77-7
Chemical Name
RuPhos Pd G3
Synonyms
RuPhos-Pd-G3;RuPhos Palladacycle Gen.3;Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);RuPhos Pd G3;RuPhos Pd G3 95%;RuPhos-G3-Palladacycle;RuPhos Pd G3 ISO 9001：2015 REACH;Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-...;Methanesulfonato(2-Dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II);(2-Dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
CBNumber
CB02686116
Molecular Formula
C43H57NO5PPdS-
Formula Weight
837.375141
MOL File
1445085-77-7.mol
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RuPhos Pd G3 Property

Melting point:
188-196°C (decomposition)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
Powder
color 
white
InChIKey
GYTUQNMMIUJBSP-UHFFFAOYSA-N
CAS DataBase Reference
1445085-77-7
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-52/53
Safety Statements 
26-61
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
763403
Product name
RuPhos Pd G3
Purity
95%
Packaging
1g
Price
$248
Updated
2024/03/01
Sigma-Aldrich
Product number
763403
Product name
RuPhos Pd G3
Purity
95%
Packaging
5g
Price
$1000
Updated
2024/03/01
Strem Chemicals
Product number
46-0314
Product name
Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RuPhos Palladacycle Gen. 3]
Packaging
250mg
Price
$64
Updated
2024/03/01
Strem Chemicals
Product number
46-0314
Product name
Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RuPhos Palladacycle Gen. 3]
Packaging
1g
Price
$209
Updated
2024/03/01
Sigma-Aldrich
Product number
763403
Product name
RuPhos Pd G3
Purity
95%
Packaging
250mg
Price
$88.4
Updated
2024/03/01
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RuPhos Pd G3 Chemical Properties,Usage,Production

Reaction

  1. Palladium catalyst used for facile, C-N cross-coupling reactions.
  2. A practical synthesis of indoles via a Pd-catalyzed C-N ring formation.

Uses

RuPhos Pd G3 can be used as a pre-catalyst in the following protocols:

  • Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles.
  • Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers.
  • Suzuki-Miyaura-cross-coupling of aminothiophenes.

General Description

RuPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

RuPhos Pd G3 Preparation Products And Raw materials

Raw materials

Preparation Products

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RuPhos Pd G3 Suppliers

China 125 United States 10 Global 135
Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
Advantage
60
Alfa Chemistry
Tel
+1-5166625404
Fax
1-516-927-0118
Email
Info@alfa-chemistry.com
Country
United States
ProdList
21317
Advantage
58
Accela ChemBio Inc.
Tel
(+1)-858-699-3322
Fax
(+1)-858-876-1948
Email
info@accelachem.com
Country
United States
ProdList
19965
Advantage
58
Protheragen-ING
Tel
+16313385890
Email
info@protheragen-ing.com
Country
United States
ProdList
1091
Advantage
58
Aladdin Scientific
Tel
+1-833-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
52927
Advantage
58
Aladdin Scientific
Tel
+1-833-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57511
Advantage
58
Aceschem Inc.
Tel
+1-817863-6948 +1-（817）863-6948
Email
sales@aceschem.com
Country
United States
ProdList
19639
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58
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View Lastest Price from RuPhos Pd G3 manufacturers

Wuhan LPBchem Technology Co.,Ltd
Product
Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl）palladium(II) / RuPhos Pd G3 1445085-77-7
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2020-11-25
Longyan Tianhua Biological Technology Co., Ltd
Product
RuPhos Pd G3 1445085-77-7
Price
US $65.00/KG
Min. Order
1KG
Purity
99
Supply Ability
10000KG
Release date
2020-11-10
Career Henan Chemical Co
Product
RuPhos Pd G3 1445085-77-7
Price
US $3.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-10

1445085-77-7, RuPhos Pd G3Related Search:

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  • Buchwald Ligands&Precatalysts
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